Fifty-six samples representing 6 sediment cores taken along the N.W. European Continental Margin from the shelf, slope and abyssal plain of the Goban Spur and Meriadzek Terrace were quantitatively analysed for total hydrolyzable amino acids (THAA) and clay minerals. In descending order, the five most abundant amino acids making up more than 70% of the total were: aspartic acid, glycine, serine, alanine and glutamic acid. Clay mineral proportions were typical for the N.E. Atlantic, in order of descending abundance: illite, kaolinite, chlorite, smectite and mixed layers.The Meriadzek Terrace area is characterised by fine grain suspension sedimentation with a low pelagic carbonate input and the lowest content of THAA. In contrast, the Goban Spur transect is characterised by much higher carbonate inputs and more vigorous hydrodynamics as judged from granulometry and the high abundance of minerals of shelf and continental origin and a generally higher THAA content. The pelagic portion of THAA deposited at the sea floor is more readily mineralised during early diagenesis than the more ‘refractory', clay mineral-associated continental portion. Along this margin the average mineralization of THAA down to 25 cm in the sediment is about 54%. There is a significant affinity between chlorites and amino acids which we suggest may involve the formation of ionic bonds between the octahedral layers of the clay and the amino acids. 相似文献
Nonlinear finite element (FE) modeling has been widely used to investigate the effects of seismic isolation on the response of bridges to earthquakes. However, most FE models of seismic isolated bridges (SIB) have used seismic isolator models calibrated from component test data, while the prediction accuracy of nonlinear FE models of SIB is rarely addressed by using data recorded from instrumented bridges. In this paper, the accuracy of a state‐of‐the‐art FE model is studied through nonlinear FE model updating (FEMU) of an existing instrumented SIB, the Marga‐Marga Bridge located in Viña del Mar, Chile. The seismic isolator models are updated in 2 phases: component‐wise and system‐wise FEMU. The isolator model parameters obtained from 23 isolator component tests show large scatter, and poor goodness of fit of the FE‐predicted bridge response to the 2010 Mw 8.8 Maule, Chile Earthquake is obtained when most of those parameter sets are used for the isolator elements of the bridge model. In contrast, good agreement is obtained between the FE‐predicted and measured bridge response when the isolator model parameters are calibrated using the bridge response data recorded during the mega‐earthquake. Nonlinear FEMU is conducted by solving single‐ and multiobjective optimization problems using high‐throughput cloud computing. The updated FE model is then used to reconstruct response quantities not recorded during the earthquake, gaining more insight into the effects of seismic isolation on the response of the bridge during the strong earthquake. 相似文献
This paper deals with the design of optimal spatial sampling of water quality variables in remote regions, where logistics are complicated and the optimization of monitoring networks may be critical to maximize the effectiveness of human and material resources. A methodology that combines the probability of exceeding some particular thresholds with a measurement of the information provided by each pair of experimental points has been introduced. This network optimization concept, where the basic unit of information is not a single spatial location but a pair of spatial locations, is used to emphasize the locations with the greatest information, which are those at the border of the phenomenon (for example contamination or a quality variable exceeding a given threshold), that is, where the variable at one of the locations in the pair is above the threshold value and the other is below the threshold. The methodology is illustrated with a case of optimizing the monitoring network by optimal selection of the subset that best describes the information provided by an exhaustive survey done at a given moment in time but which cannot be repeated systematically due to time or economic constrains. 相似文献
This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.
This contribution analyses the processes involved in the generation of sinkholes from the study of paleokarst features exposed
in four Spanish Tertiary basins. Bedrock strata are subhorizontal evaporites, and in three of the basins they include halite
and glauberite in the subsurface. Our studies suggest that formation of dolines in these areas results from a wider range
of subsidence processes than those included in the most recently published sinkhole classifications; a new genetic classification
of sinkholes applicable to both carbonate and evaporite karst areas is thus proposed. With the exception of solution dolines,
it defines the main sinkhole types by use of two terms that refer to the material affected by downward gravitational movements
(cover, bedrock or caprock) and the main type of process involved (collapse, suffosion or sagging). Sinkholes that result
from the combination of several subsidence processes and affect more than one type of material are described by combinations
of the different terms with the dominant material or process followed by the secondary one (e.g. bedrock sagging and collapse
sinkhole). The mechanism of collapse includes any brittle gravitational deformation of cover and bedrock material, such as
upward stoping of cavities by roof failure, development of well-defined failure planes and rock brecciation. Suffosion is
the downward migration of cover deposits through dissolutional conduits accompanied with ductile settling. Sagging is the
ductile flexure of sediments caused by differential corrosional lowering of the rockhead or interstratal karstification of
the soluble bedrock. The paleokarsts we analysed suggest that the sagging mechanism (not included in previous genetic classifications)
plays an important role in the generation of sinkholes in evaporites. Moreover, collapse processes are more significant in
extent and rate in areas underlain by evaporites than in carbonate karst, primarily due to the greater solubility of the evaporites
and the lower mechanical strength and ductile rheology of gypsum and salt rocks. 相似文献